ORIGINAL RESEARCH
Transport of Nitrogen Compounds through
Subsoils in Agricultural Areas:
Column Tests
Joanna Fronczyk, Anna Sieczka, Mariusz Lech, Maja Radziemska, Zbigniew Lechowicz
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Faculty of Civil and Environmental Engineering, Warsaw University of Life Sciences,
Nowoursynowska 159, 02-776 Warsaw, Poland
Submission date: 2016-01-29
Final revision date: 2016-03-22
Acceptance date: 2016-03-22
Publication date: 2016-07-22
Pol. J. Environ. Stud. 2016;25(4):1505-1514
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ABSTRACT
Soil parameters in agricultural areas play an important role in the migration of nitrogen compounds
to groundwater. Nitrogen loss from subsoil depends on soil permeability, organic content, and soil saturation.
Our study evaluates the parameters controlling the migration of nitrogen compounds through selected
fine and sandy soils that may affect the quality of groundwater in agricultural areas. The results of this
study indicate that denitrification processes that substantially affect ammonium (NH4+) and nitrate (NO3-)
concentrations take place in fine soils. These processes decrease the flow of nitrogen into groundwater and
are indicated by the production of a gashouse phase, a decrease in hydraulic conductivity, and a nitrogen
compound concentration in the filtrate that is lower than the maximum concentration. Column tests have
shown that the dominant transport process for silt loam and sand samples was advection, and the dominant
transport process for loam was dispersion. Moreover, the velocities of NH4+ ion transport were lower
than the velocities of water flow by approximately seven and five times for loam and sand, respectively.
The estimated values of the retardation factor and dynamic sorption capacity for NO3- were lower than
those for NH4+ ions. Finally, groundwater located below the silt loam and loam soil layers can effectively
be protected against the infiltration of nitrogen compounds from agricultural sources.