ORIGINAL RESEARCH
Toxicity of Bromate Ions in Drinking Water
and its Determination Using Ion Chromatography
with Post Column Derivatisation
drinking quality.
R. Michalski*
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Institute of Environmental Engineering of Polish Academy of Science,
Curie-Skłodowskiej 34, 41-819 Zabrze, Poland
Pol. J. Environ. Stud. 2003;12(6):727-734
KEYWORDS
ABSTRACT
Disinfection of drinking water is usually carried out by chlorination. This is a well-known and effective
technology which has many advantages. However, during this process dangerous by-products such as
trihalomethanes, as well as chlorate and chlorite are formed.
The disinfection of bromide-containing source waters with ozone results in the production of bromate
ions (BrO3
-), which are formed as a result of a series of complex reactions between ozone and bromide ions
present in water. Bromates are possible human carcinogens. For these reasons trace analysis of bromate and
other oxyhalides by-products in waters has received considerable attention in recent years.
This article describes the determination of bromate in drinking water by IC with post column derivatisation
using NaBr/NaNO2 and UV detection. The direct method allows the determination of bromate at low
ěg/dm3 levels and sample pretreatment is not necessary.