REVIEW PAPER
The Use of Phenolic Wastewater
in Coke Production
Anna Kwiecińska, Jan Figa, Sławomir Stelmach
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Institute for Chemical Processing of Coal,
Zamkowa 1, 41-803 Zabrze, Poland
Submission date: 2014-10-16
Final revision date: 2015-11-10
Acceptance date: 2015-11-24
Publication date: 2016-03-17
Pol. J. Environ. Stud. 2016;25(2):465-470
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ABSTRACT
The huge amount of phenolic wastewater generated at coke oven plants is nowadays partially utilized
during the wet coke quenching process. The stream, however, contains a range of inorganic compounds (i.e.,
chlorides, alkali and sulphates), the presence of which in the coke is highly undesired. Moreover, the impact
on the quenching water composition on the final quality of coke, considering the concentrations of mineral
contaminants, is unknown. Our paper investigates the composition of quenching water – in particular the impact
of chlorides and sodium ion content on the final quality of wet-quenched coke. We used dry-quenched
coke, treated rainfall, and treated phenolic wastewater generated at one the largest coke plants in Poland.
Our study showed the existence of linear dependences between chlorides and sodium ion content in quenching
water, and their fi nal amount in the wet-quenched coke. We developed the calculation procedure of the
maximum share of the treated phenolic wastewater in the quenching water stream, at which the contract
parameter of coke could be held, based on the basis of our experimental results.