ORIGINAL RESEARCH
The Influence of Chemical Modification
on the Co2+ Ion Sorption Process
by Anaerobic Sludge
Vladimír Frišták, Michaela Valovčiaková, Martin Pipíška, Juraj Lesný
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Department of Ecochemistry and Radioecology, Faculty of Natural Sciences,
University of SS. Cyril and Methodius in Trnava,
Nám. J. Herdu 2, SK-917 01, Trnava, Slovak Republic
Pol. J. Environ. Stud. 2014;23(3):705-712
KEYWORDS
ABSTRACT
Modification by chemical agents affected the sorption capacities of sludge from municipal wastewater
treatment plants (WWTPs). We tried to characterize changes in sorption capacity of dried anaerobic sludge
(DANS) after chemical modification by formaldehyde, methanol, and hydrochloric acid. Modified sludges
were characterized by FT-IR spectroscopy, cation exchange capacity, and electrothermal atomic absorption
spectrometry (ETAAS) analysis. Maximum sorption capacities Qmax at pH 6.0 for Co2+ ions calculated from
Langmuir isotherm model were 175±5 μmol/g for unmodified DANS, 170±2 μmol/g for CH2O-modified
DANS, 12±0.2 μmol/g for CH3OH-modified DANS, and 15±0.3 μmol/g for HCl-modified DANS. Our paper
established the crucial role of carboxyl functional groups against amino and hydroxyl groups in sorption
process of cobalt ions.