ORIGINAL RESEARCH
Study on the Adsorption of Heavy Metals in Sludge
by Calcium Alginate Cross-Linked
Zeolite Microspheres
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1
School of Architecture and Civil Engineering, Xi’an University of Science and Technology, Xi’an 710054, China
2
School of Metallurgy, Xi’an University of Architecture and Technology, Xi’an 710055, China
3
College of Energy and Environmental Engineering, Hebei University of Engineering, Handan 056038, China
4
Innovation Center for Water Pollution Control and Water Ecological Remediation, Hebei University of Engineering,
Handan 056038, China
Submission date: 2020-09-29
Final revision date: 2020-12-03
Acceptance date: 2020-12-03
Online publication date: 2021-05-12
Publication date: 2021-07-07
Corresponding author
Beibei Chai
College of Energy and Environmental Engineering, Hebei University of Engineering, China
Pol. J. Environ. Stud. 2021;30(4):3777-3786
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ABSTRACT
This study successfully prepared a calcium alginate cross-linked zeolite microsphere, a heavy metal
adsorbent, to reduce the harmful heavy metal content in sludge and improve the efficiency of sludge
resource utilization. The effects of temperature, dosage, and stirring time on the adsorption effect
were investigated by atomic absorption spectrophotometry and BCR (European Community Bureau
of Reference) method, and the ecological risk of heavy metals in sludge before and after treatment
was evaluated via the geoaccumulation index. The following results were obtained: after the sludge
was treated with calcium alginate cross-linked zeolite microspheres, the total amount of heavy metals
decreased, and the proportion of stable state increased. At temperatures within 10ºC-25ºC, the following
trend was observed: the higher the temperature, the higher the adsorption efficiency. When the dosage
was controlled at 0.5-2 g/500 ml and the stirring time was 2-3 h, a good adsorption effect was achieved.
The pollution level of Pb and Zn in the sludge was reduced after adsorption treatment from unpolluted
to moderately polluted to unpolluted, and that of Cd and Cu was reduced from moderately to heavily
polluted to moderately polluted.