ORIGINAL RESEARCH
Pollution and Carbon Sequestration
of Highway Runoff in Karst Regions:
A Case Study from Guangxi, China
More details
Hide details
1
Guangxi Xinfazhan Communication Group Co., Ltd., Nanning 530029, China
2
Institute of Karst Geology, Chinese Academy of Geological Sciences, Key Laboratory of Karst Dynamics,
Ministry of Natural Resources & Guangxi Zhuang Autonomous Region, International Research Centre on Karst,
UNESCO, Guilin, Guangxi 541004, China
3
Pingguo Guangxi, Karst Ecosystem, National Observation and Research Station, Pingguo 531406, Guangxi, China
Submission date: 2024-04-29
Final revision date: 2024-05-28
Acceptance date: 2024-06-12
Online publication date: 2024-10-07
Publication date: 2025-05-09
Corresponding author
Fen Huang
Institute of Karst Geology, Chinese Academy of Geological Sciences, Key Laboratory of Karst Dynamics,
Ministry of Natural Resources & Guangxi Zhuang Autonomous Region, International Research Centre on Karst,
UNESCO, Guilin, Guangxi 541004, China
Pol. J. Environ. Stud. 2025;34(4):4083-4094
KEYWORDS
TOPICS
ABSTRACT
Highway runoff is a known source of pollution; however, its ability to sequester carbon is less well
understood. In this study, we examined the pollution, sources, and carbon sequestration of highway
runoff in karst areas of Guangxi, China. Runoff samples were collected from different locations during
the rainy season. Suspended solids, CODMn, NH3–N, and Mn were identified as the primary pollutants.
Factor analysis revealed five main sources of highway runoff: traffic, construction, carbonate weathering,
rainfall combined with artificial fertilizers, and artificial fertilizers alone. Traffic and carbonate
weathering emerged as the predominant factors in the Yaji section of the Guilin Ring Expressway (YJ) and
adjacent to the Baizhujing Reservoir (BZJ), while construction and carbonate weather were the primary
factors in Xincheng County (XC). The carbon sequestration capacity of highway runoff was the highest
in XC, followed by BZJ and YJ. YJ and BZJ accounted for 15-21% of that observed in a karst spring
in the same region, revealing a 3.44-4.64–fold increase compared to silicate basins. Thus, despite being
a source of pollution, the function of highway runoff as a carbon sink may be key to emission reduction
efforts.
CONFLICT OF INTEREST
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
REFERENCES (49)
1.
JIA Z., WANG J., ZHOU X., ZHOU Y., LI Y., LI B., ZHOU S. Identification of the sources and influencing factors of potentially toxic elements accumulation in the soil from a typical karst region in Guangxi, Southwest China. Environmental Pollution, 256, 113505, 2020.
https://doi.org/10.1016/j.envp... PMid:31706759.
2.
MÜLLER A., ÖSTERLUND H., MARSALEK J., VIKLANDER M. The pollution conveyed by urban runoff: A review of sources. Science of the Total Environment, 709, 136125, 2020.
https://doi.org/10.1016/j.scit... PMid:31905584.
3.
HUBER M., WELKER A., HELMREICH B. Critical review of heavy metal pollution of traffic area runoff: Occurrence, influencing factors, and partitioning. Science of the Total Environment, 541, 895, 2016.
https://doi.org/10.1016/j.scit... PMid:26448594.
4.
CHARTERS F.J., COCHRANE T.A., O'SULLIVAN A.D. The influence of urban surface type and characteristics on runoff water quality. Science of The Total Environment, 755, 142470, 2021.
https://doi.org/10.1016/j.scit... PMid:33035981.
5.
THORPE A., HARRISON R.M. Sources and properties of non-exhaust particulate matter from road traffic: A review. Science of the Total Environment, 400 (1-3), 270, 2008.
https://doi.org/10.1016/j.scit... PMid:18635248.
6.
PETRUCCI G., GROMAIRE M.C., SHORSHANI M.F., CHEBBO G. Nonpoint source pollution of urban stormwater runoff: a methodology for source analysis. Environmental Science and Pollution Research, 21 (17), 10225, 2014.
https://doi.org/10.1007/s11356... PMid:24760596.
7.
OMRANI M., RUBAN V., RUBAN G., LAMPREA K. Assessment of atmospheric trace metal deposition in urban environments using direct and indirect measurement methodology and contributions from wet and dry depositions. Atmospheric Environment, 168, 101, 2017.
https://doi.org/10.1016/j.atmo....
8.
KAYHANIAN M. Trend and concentrations of legacy lead (Pb) in highway runoff. Environmental Pollution, 160, 169, 2012.
https://doi.org/10.1016/j.envp... PMid:22035941.
9.
MARKIEWICZ A., BJÖRKLUND K., ERIKSSON E., KALMYKOVA Y., STRÖMVALL A.M., SIOPI A. Emissions of organic pollutants from traffic and roads: Priority pollutants selection and substance flow analysis. Science of the Total Environment, 580, 1162, 2017.
https://doi.org/10.1016/j.scit... PMid:28038877.
10.
HORTON A.A., WALTON A., SPURGEON D.J., LAHIVE E., SVENDSEN C. Microplastics in freshwater and terrestrial environments: Evaluating the current understanding to identify the knowledge gaps and future research priorities. Science of the Total Environment, 586, 127, 2017.
https://doi.org/10.1016/j.scit... PMid:28169032 PMCid:PMC10088809.
11.
DE SILVA S., BALL A.S., HUYNH T., REICHMAN S.M. Metal accumulation in roadside soil in Melbourne, Australia: Effect of road age, traffic density and vehicular speed. Environmental Pollution, 208, 102, 2016.
https://doi.org/10.1016/j.envp... PMid:26603093.
12.
MURPHY L.U., COCHRANE T.A., O'SULLIVAN A. Build-up and wash-off dynamics of atmospherically derived Cu, Pb, Zn and TSS in stormwater runoff as a function of meteorological characteristics. Science of the Total Environment, 508, 206, 2015.
https://doi.org/10.1016/j.scit... PMid:25478658.
13.
PERERA T., MCGREE J., EGODAWATTA P., JINADASA K., GOONETILLEKE A. New conceptualisation of first flush phenomena in urban catchments. Journal of Environmental Management, 281, 111820, 2021.
https://doi.org/10.1016/j.jenv... PMid:33360584.
14.
BAKR A.R., FU G.Y., HEDEEN D. Water quality impacts of bridge stormwater runoff from scupper drains on receiving waters: A review. Science of the Total Environment, 726, 138068, 2020.
https://doi.org/10.1016/j.scit... PMid:32335398.
15.
HUANG F., WEI X., ZHU T., LUO Z., CAO J. Insights into Distribution of Soil Available Heavy Metals in Karst Area and Its Influencing Factors in Guilin, Southwest China. Forests, 12 (5), 609, 2021.
https://doi.org/10.3390/f12050....
16.
WEN Y., LI W., YANG Z., ZHUO X., JI J. Evaluation of various approaches to predict cadmium bioavailability to rice grown in soils with high geochemical background in the karst region, Southwestern China. Environmental Pollution, 258, 113645, 2020.
https://doi.org/10.1016/j.envp... PMid:31796323.
17.
CAO J., WU X., HUANG F., HU B., GROVES C., YANG H., ZHANG C. Global significance of the carbon cycle in the karst dynamic system: evidence from geological and ecological processes. China Geology, 17, 2018.
https://doi.org/10.31035/cg201....
18.
SUN P., HE S., YU S., PU J., YUAN Y., ZHANG C. Dynamics in riverine inorganic and organic carbon based on carbonate weathering coupled with aquatic photosynthesis in a karst catchment, Southwest China. Water Research, 189, 116658, 2021.
https://doi.org/10.1016/j.watr... PMid:33249310.
19.
SUN P.A., XIAO Q., GUO Y., MIAO Y., WANG Q., CHENG Z. Carbonate dissolution rate and karst carbon sink in mixed carbonate and silicate terrain: Take the upper reaches of the Lijiang River basin as an example. Carsologica Sinica, 40 (5), 825, 2021 [in Chinese].
20.
HUANG F., ZHANG C.L., XIE Y.C., LI L., CAO J.H. Inorganic carbon flux and its source in the karst catchment of Maocun, Guilin, China. Environmental Earth Sciences, 74 (2), 1079, 2015.
https://doi.org/10.1007/s12665....
21.
DING M., WU X., CAO J., HU X., PAN M., HUANG F., REN M. Characteristics and influencing factors of vertical carbon migration in the cave system of Liangfeng cave in Guilin. Carsologica Sinica, 40 (4), 600, 2021 [in Chinese].
22.
CEN H., QIU R., YANG P. Discussion on Soil Buffering Mechanisms of Acid Precipitation. Research of Environmental Sciences, 13 (2), 49, 2000.
23.
KIM J.H., JOBBÁGY E.G., RICHTER D.D., TRUMBORE S.E., JACKSON R.B. Agricultural acceleration of soil carbonate weathering. Global Change Biology, 26 (10), 5988, 2020.
https://doi.org/10.1111/gcb.15... PMid:32511819.
24.
WANG F., LAI H.X., LI Y.B., FENG K., TIAN Q.Q., GUO W.X., QU Y.P., YANG H.B. Spatio-temporal evolution and teleconnection factor analysis of groundwater drought based on the GRACE mascon model in the Yellow River Basin. Journal of Hydrology, 626, 2023.
https://doi.org/10.1016/j.jhyd....
25.
ZENG S., LIU Z., KAUFMANN G. Sensitivity of the global carbonate weathering carbon-sink flux to climate and land-use changes. Nature Communications, 10 (1), 5749, 2019.
https://doi.org/10.1038/s41467... PMid:31848344 PMCid:PMC6917807.
26.
The Ministry of Environmental Protection of the People's Republic of China. Environmental quality standards for surface water, GB3838-2002, 2002.
27.
General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China. The reuse of urban recycling water - Water quality standard for scenic environment use, GB/T 18921-2019, 2019 [In Chinese].
28.
SMITH K.P., SORENSON J.R., GRANATO G.E. Characterization of stormwater runoff from bridge decks in eastern Massachusetts, 2014-16. US Geological Survey, 2018.
https://doi.org/10.3133/sir201....
29.
LI Q. Research on Pollution Characteristics and Treatment Countermeasures of Runoff Based on Liuzhen Express in Guizhou Province. Beijing, 2018 [in Chinese].
30.
LI H., ZHANG X., GAO H., FU D. Characterization of contaminated runoff on free way surface. China Environmental Science, 28 (11), 1037, 2008 [In Chinese].
31.
WESTERLUND C., VIKLANDER M., BÄCKSTRÖM M. Seasonal variations in road runoff quality in Lulea, Sweden. Water Science and Technology, 48 (9), 93, 2003.
https://doi.org/10.2166/wst.20....
32.
ZHU T., ZENG S., QIN H., ZHOU K., YANG H., LAN F., HUANG F., CAO J., MÜLLER C. Low nitrate retention capacity in calcareous soil under woodland in the karst region of southwestern China. Soil Biology & Biochemistry, 97, 99, 2016.
https://doi.org/10.1016/j.soil....
33.
REDWAN M., MONEIM A.A.A. Factors controlling groundwater hydrogeochemistry in the area west of Tahta, Sohag, Upper Egypt. Journal of African Earth Sciences, 118, 328, 2016.
https://doi.org/10.1016/j.jafr....
35.
XIAO J., JIN Z.D., WANG J., ZHANG F. Hydrochemical characteristics, controlling factors and solute sources of groundwater within the Tarim River Basin in the extreme arid region, NW Tibetan Plateau. Quaternary International, 380, 237, 2015.
https://doi.org/10.1016/j.quai....
36.
GONG X.Y., WENG B.S., YAN D.H., YANG Y.H., YAN D.M., NIU Y.Z., WANG H. Potential recharge sources and origin of solutes in groundwater in the central Qinghai-Tibet Plateau using hydrochemistry and isotopic data. Journal of Hydrology-Regional Studies, 40, 2022.
https://doi.org/10.1016/j.ejrh....
37.
LI Z.J., LI Z.X., FAN X.J., WANG Y., SONG L.L., GUI J., XUE J., ZHANG B.J., GAO W.D. Transformation mechanism of ions on different waters in alpine region. Chemosphere, 248, 2020.
https://doi.org/10.1016/j.chem... PMid:32032884.
38.
ZHU H., LI Y., WU L., YU S., XIN C., SUN P., XIAO Q., ZHAO H., ZHANG Y., QIN T. Impact of the atmospheric deposition of major acid rain components, especially NH4, on carbonate weathering during recharge in typical karst areas of the Lijiang River basin, southwest China. Applied Geochemistry, 114, 104518, 2020.
https://doi.org/10.1016/j.apge....
39.
TAO L.C., CUN D.X., TU C.L., MA Y.Q., LIU Z.N., YIN L.H., HE C.Z., PANG L., ZHANG Q.D. Hydrochemical Characteristics and Control Factors of Surface Water in Kuaize River Basin at the Upper Pearl River. Environmental Science, 44 (11), 6025, 2023.
40.
HAN G.L., LIU C.Q. Water geochemistry controlled by carbonate dissolution: a study of the river waters draining karst-dominated terrain, Guizhou Province, China. Chemical Geology, 204 (1-2), 1, 2004.
https://doi.org/10.1016/j.chem....
41.
LI Z.X., QI F., WANG Q.J., SONG Y., LI H.Y., LI Y.G. The influence from the shrinking cryosphere and strengthening evopotranspiration on hydrologic process in a cold basin, Qilian Mountains. Global and Planetary Change, 144, 119, 2016.
https://doi.org/10.1016/j.glop....
42.
LI Z.J., SONG L.L., MA J.Z. Hydrochemical characteristics and environmental significance in different ablation period in Hulugou River Basin in Qilian Mountain. Environmental Earth Sciences, 76 (17), 2017.
https://doi.org/10.1007/s12665....
44.
SAJJAD R.U., PAULE-MERCADO M.C., SALIM I., MEMON S., SUKHBAATAR C., LEE C.H. Temporal variability of suspended solids in construction runoff and evaluation of time-paced sampling strategies. Environmental Monitoring and Assessment, 191 (2), 2019.
https://doi.org/10.1007/s10661... PMid:30689056.
45.
SU C., YANG Y., BA J., LUO F., LI X., ZHAO G. Dynamic characteristics and genesis of strontium-rich groundwater in Xintian county, Hunan Province. Carsologica Sinica, 39 (1), 24, 2020 [in Chinese].
46.
PENG X.D., DAI Q.H., LI C.L., XU S.B. The underground leakage process of soil patches around bedrock outcrops in a karst rocky desertification area traced using rare earth elements. Journal of Hydrology, 619, 2023.
https://doi.org/10.1016/j.jhyd....
47.
HUANG C.Y. Soil Science. China Argiculture Press, Beijing, 2000.
48.
XIN C. Characteristics of karst hydrochemistry and carbon sink at Yaji test site, Guilin. Northwest Normal University, Lanzhou, 2023 [in Chinese].
49.
KANG Z., CHEN J., YUAN D., HE S., LI Y., CHANG Y., DENG Y., CHEN Y., LIU Y., JIANG G., WANG X., ZHANG Q. Promotion function of forest vegetation on the water & carbon coupling cycle in karst critical zone: Insights from karst groundwater systems in south China. Journal of Hydrology, 590, 125246, 2020.
https://doi.org/10.1016/j.jhyd....