ORIGINAL RESEARCH
Partial Substitution of Lime-Dried Sludge
as a Flux for Cement Sintering Ingredients
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1
Shanghai Shenhuan Environment Engineering Co., Ltd. Shanghai 200092, China
2
Shanghai Construction Environmental Technology Co., Ltd. Shanghai 200063, China
3
Eco-Environmental Science Research and Design Institute of Zhejiang Province, Hangzhou 310007, PR China
4
State Key Laboratory of Pollution Control and Resources Reuse, College of Environmental Science and Engineering,
Tongji University, Shanghai 200092, PR China
Submission date: 2023-08-01
Final revision date: 2023-10-22
Acceptance date: 2023-11-11
Online publication date: 2024-02-09
Publication date: 2024-03-18
Corresponding author
Wei Xu
Shanghai Shenhuan Environment Engineering Co., Ltd. Shanghai 200092, China
Guang Ming Li
State Key Laboratory of Pollution Control and Resources Reuse, College of Environmental Science and Engineering,
Tongji University, Shanghai 200092, PR China
Pol. J. Environ. Stud. 2024;33(3):2927-2937
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ABSTRACT
Municipal sewage sludge has a high content of phosphorus, which has a high utilization value.
However, this useful resource is always wasted during sludge landfill and incineration processes.
In this study, lime was used to regulate the stability of sludge and lime-dried sludge (LDS) was used
as a substitute for raw meal and sintering additive for cement clinker production. The variation of
phosphorus content or concentration and its threshold level in LDS was investigated. The results showed
that after lime drying, 90% of the phosphorus in the sludge existed in the form of inorganic phosphorus
(IP), of which 80% was in the stable apatite state. More than 85% of the phosphorus in LDS was eutectic
with clinker, avoiding secondary pollution in the synergistic process of cement kiln. The addition
of LDS as a phosphorus sintering flux for clinker plays a good role in promoting the formation of
bauxite in clinker and improving the burnability of raw materials. The addition of up to 15 wt.% of LDS
containing 0.53% P2O5 to cement raw meal does not affect the clinker reaction. As an important flux
in cement production, LDS can save phosphate rock and replace flux as a cement sintering ingredient.