ORIGINAL RESEARCH
Kinetic Behaviour of the Activated Sludge Process
Used for Treating Composite Chrome Tannery
Wastewater
Supriyo Goswami, Debabrata Mazumder
More details
Hide details
Civil Engineering Department, Indian Institute of Engineering Science and Technology,
Shibpur P.O.– Botanic Garden, Howrah – 711 103, India
Submission date: 2015-06-08
Final revision date: 2015-08-24
Acceptance date: 2015-08-25
Publication date: 2015-11-27
Pol. J. Environ. Stud. 2015;24(6):2405-2409
KEYWORDS
TOPICS
ABSTRACT
Chrome tannery wastewater poses a serious environmental threat due to its high chemical oxygen
demand (COD), bio-chemical oxygen demand (BOD5), nitrogen, total suspended solids (TSS), chromium, sulphide,
chloride, etc. As a result, the composite chrome tannery wastewater is not treated satisfactorily in most
cases owing to various toxic/inhibitory substances. Out of various biological methods available for the treatment
of composite chrome tannery wastewater, the activated sludge process (ASP) is a proven technology.
The process design of the ASP reactor with rational approach always warrants authentic values of kinetic coefficients
regarding substrate removal and biomass growth. Therefore, the kinetic behaviour of substrate
(i.e. COD) removal and biomass growth must be established prior to use of any model. Apart from this, the
biodegradation potential of the concerned wastewater needs to be adjudged to take appropriate measures during
treatment. The present study was performed to examine the treatability of the composite chrome tannery
wastewater using an acclimated suspended biomass under batch mode of operation. The study also aims to
determine the kinetic co-efficient for biodegradation based on the most favourable kinetic model. A laboratory-
scale ASP reactor was run for conducting the batch study on COD removal from composite tannery wastewater
and also for determining the kinetic coefficients. The results of several batch experiments revealed the
efficacy of the ASP system in treating composite chrome tannery wastewater, but some inhibition was also
noticed. Consequently, the Haldane growth kinetic model was found best fitting for biodegradation of chrome
tannery wastewater using mixed microorganisms. The batch study was carried out under varying batch periods
to determine five kinetics constants, viz. Ks, k, ki, Y, and kd from the experimental data. The values of all
the kinetic coefficients are tallying with past kinetic studies on composite tannery wastewater.