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ORIGINAL RESEARCH
Development of Ammonium-Based Ion Exchange
Polymer for Phosphate Ions Removal
1
Department of Chemical Engineering, Faculty of Industrial Technology, Universitas Ahmad Dahlan, Jalan Jend. Ahmad
Yani, Banguntapan, Tamanan, Bantul, DI Yogyakarta, Indonesia 55191
2
Department of Physics, Faculty of Applied Science and Technology, Universitas Ahmad Dahlan, Jalan Jend. Ahmad
Yani, Banguntapan, Tamanan, Bantul, DI Yogyakarta, Indonesia 55191
3
Graduate School of Engineering, Gifu University, Yanagido 1-1, Gifu Shi, Gifu Ken, Japan 501-1193
Submission date: 2024-07-18
Final revision date: 2024-10-05
Acceptance date: 2024-11-14
Online publication date: 2025-02-27
Publication date: 2026-01-30
Corresponding author
Dhias Cahya Hakika
Department of Chemical Engineering, Faculty of Industrial Technology, Universitas Ahmad Dahlan, Jalan Jend. Ahmad Yani, Banguntapan, Tamanan, Bant, 55191, Yogyakarta, Indonesia
Department of Chemical Engineering, Faculty of Industrial Technology, Universitas Ahmad Dahlan, Jalan Jend. Ahmad Yani, Banguntapan, Tamanan, Bant, 55191, Yogyakarta, Indonesia
Pol. J. Environ. Stud. 2026;35(1):795-804
KEYWORDS
TOPICS
ABSTRACT
Polymers can exhibit adsorbent behavior and are used to remove pollutants from environments.
Their adsorption properties can be tailored to capture specific contaminants effectively. In this research,
an ammonium-based ion exchange polymer was developed using the one-pot approach method. It
allows for simultaneous polymerization and functionalization, reducing the number of reaction steps
and purification processes. The developed ammonium-based polymer is a novelty material for removing
phosphate ions from an aqueous solution. Several essential factors (temperature, contact time, initial
phosphate concentration, and adsorbent dosage) that affect the removal process of phosphate ions during
adsorption were investigated. This research aims to develop a novel organic polymer using the one-pot
approach for removing phosphate from aqueous solutions and performing adsorption behavior based
on isotherm studies. The characterization of ammonium-based polymer was carried out using Fourier
Transform Infrared (FTIR) and Scanning Electron Microscopy (SEM), which offered proof of chemical
and physical adsorption. The optimum condition during phosphate adsorption using a developed
ammonium-based polymer was at a temperature of 25°C, contact time of 20 minutes, initial phosphate
concentration of 30 ppm, and adsorbent dosage of 0.05 g, which achieved adsorption capacity (Qe) of
2.99 mg/g and phosphate ion removal percentage of 99.73%. The Langmuir model describes the best
adsorption isotherm of phosphate ions on the adsorbent with coefficient value (R2=0.9974). In the
future, it can offer an alternative method for treating ion phosphate in aqueous solution or wastewater
treatment.
CONFLICT OF INTEREST
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
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