ORIGINAL RESEARCH
Degradation of MCPA in Soil Horizons
of Polish Agricultural Soils
T. Paszko
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Department of Chemistry, University of Life Sciences, Akademicka 15, 20-950 Lublin, Poland
Pol. J. Environ. Stud. 2009;18(6):1083-1091
KEYWORDS
ABSTRACT
Laboratory studies on degradation of MCPA were performed in different soil horizons of three Polish
agricultural soils. Hyperdystric Arenosol (Ap, BwC, C), Haplic Luvisol (Ap, E, Bt) and Hypereutric Cambisol
(Ap, Bw, BwC) were selected for investigations as representative of Polish agricultural soils. Degradation
experiments were performed at 5 and 25°C. Fitting the data to the exponential form of the three-half kinetic
model gave good results, worse in the case of a first-order kinetic equation due to the lag-phase observed.
Therefore the zero-order kinetic equation was also used. The values of DT50 at 25°C for Ap horizons of soils
were in the range of 1.5-6.9 days, for BwC, E and Bw horizons 8.7-20.1 days, and for C, Bt and BwC 27.6-
85.8 days. The activation energies for all horizons of all soils were in the range of 47.8-67.8 kJ mol-1. The
results showed significant correlations between the zero- and first-order rate coefficients for MCPA degradation
and the contents of microbial biomass carbon, activity of the enzyme dehydrogenase and fluorescein diacetate
hydrolyse in the studied soils.