ORIGINAL RESEARCH
Coriandrum sativum Mediated Synthesis
of Mn3O4 Nanoparticles:
Structural and Antibacterial Studies
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1
Department of Chemistry, Lahore Garrison University, DHA Phase VI, Lahore, Pakistan
2
Department of Chemistry, Division of Science and Technology, University of Education Lahore Pakistan
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Institute of Chemistry, University of Sargodha, 40100, Pakistan
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Institute of Chemistry, Khwaja Fareed University of Engineering and Information Technology,
Rahim Yar Khan 64200, Pakistan
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Department of Physics, Lahore Garrison University, DHA Phase VI, Lahore, Pakistan
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Department of Zoology, College of Science, King Saud University, Riyadh 11451, Saudi Arabia
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Key Laboratory for Preparation and Application of Ordered Structured Materials of Guangdong Province,
College of Chemistry and Chemical Engineering, Shantou University, Shantou, Guangdong Province, China
Submission date: 2024-04-09
Final revision date: 2024-06-07
Acceptance date: 2024-09-04
Online publication date: 2024-11-14
Corresponding author
Shabbir Hussain
Institute of Chemistry, Khwaja Fareed University of Engineering and Information Technology,
Rahim Yar Khan 64200, Pakistan
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ABSTRACT
Mn3O4 nanoparticles (NPs) find a broad range of applications in catalysts, energy storage devices,
wastewater remediation, biosensors, photocatalysts, medical/antimicrobial agents, and in controlling
drug-resistant pathogens. In the present work, Mn3O4 NPs were successfully produced by using
a simple, cheap, and plant-mediated green synthetic route. The leaf extract of Coriandrum sativum
was treated with MnNO3.6H2O at 60oC and pH 12 to produce Mn3O4 NPs. The synthesized NPs were
characterized by XRD, FTIR SEM, and UV-Visible analyses. Their electrochemical properties were
investigated by cyclic voltammetry (CV) and they were also subjected to antibacterial evaluation
studies by the disc diffusion method. The XRD analysis revealed the tetragonal structures of Mn3O4
NPs with a crystallite size of 23.62 nm. FTIR spectroscopy displayed the Mn-O vibrations at 730
cm-1. SEM analysis verified the aggregated and flake-like morphology of Mn3O4 NPs. UV-Visible
spectroscopy revealed the absorption peaks at 232 and 360 nm, which correspond to the permissible
charge transfer transitions of O2-→Mn2+ and O2-→Mn3+, respectively. The CV curves clearly indicated
the redox reactions and the reversible behavior of Mn3O4 NPs. The antibacterial activity of Mn3O4 NPs against Staphylococcus aureus (Gram-positive) and Escherichia coli (Gram-negative) was also
evaluated using ciprofloxacin as a standard reference drug.