ORIGINAL RESEARCH
Chemical Forms and Distribution of Heavy Metals in
Core Sediments from the Gdańsk Basin, Baltic Sea
M.J. Belzunce Segarra1, P. Szefer2, M.J. Wilson3, J. Bacon3, J. Bolałek4
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1Marine Research Division (AZTI-Tecnalia), Muelle de la Herrera, Recinto Portuario s/n. 20110 Pasajes, Spain
2Department of Food Sciences, Medical University of Gdańsk, al. Gen. J Hallera 107. PL 80-416 Gdańsk, Poland
3Macaulay Land Use Research Institute, Craigiebuckler. Aberdeen AB15 8QH, Scotland
4Department of Oceanography, University of Gdańsk, al. Marsz. Piłsudskiego 48. PL 81-378 Gdynia, Poland
Pol. J. Environ. Stud. 2007;16(4):505-515
KEYWORDS
ABSTRACT
Short sediment cores (30 cm length) were taken along a transect of the Gdánsk Basin from the mouth of
the Vistula River out into the Baltic Sea in June 1996. The chemistry and mineralogy of surficial and buried
sediments were determined and Co, Cr, Cu, Fe, Mn, Ni, Pb and Zn were analyzed in total and in fractions
using a sequential extraction procedure. The bulk and clay mineralogy of the sediments were determined by
XRD and SEM. The concentrations of some of the trace metals in sediments are above pre-anthropogenic
background. In particular, the surficial samples are substantially enriched in Cu, Pb and Zn, suggesting
an anthropogenic origin. The concentrations of Cu, Pb and Zn range from 21-71 μg·g-1, 56-210 μg·g-1 and
21-83 μg·g-1, respectively. Unexpectedly, the concentrations of trace metals increase seawards within the
Gdańsk Basin. The forms of binding are different for each metal. Cobalt, Cr and Fe are mainly associated
with the residual mineral fraction of the sediment, although in samples with high Fe concentrations there is
a significant correlation with organic compounds. In contrast, Mn, Ni, Pb and Zn are predominantly associated
with oxides and the organic fractions, with a significant percentage associated with the carbonate and
exchangeable cation fractions, whilst Cu is mainly bound with the organic fraction.